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Titanium and zirconium permethylpentalene complexes, Pn*MCpRX, as ethylene polymerization catalysts

Abstract:

A family of group 4 permethylpentalene complexes, Pn∗MCpRX (M = Ti, Zr; CpR = Cp, CpMe, CptBu, CpnBu, CpMe3, Ind; X = Cl, Me), has been synthesized and fully characterized by multinuclear NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction studies. These complexes were immobilized on an insoluble polymethylaluminoxane (sMAO), MAO-modified silica (ssMAO), and a MAO-modified layered double hydroxide (LDH-MAO). The effect of substitution around the Cp ligand was examined i...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.organomet.6b00417

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More from this funder
Funding agency for:
Turner, Z
Grant:
Junior Research Fellowship.
More from this funder
Funding agency for:
Turner, Z
Grant:
Junior Research Fellowship.
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
35
Issue:
16
Pages:
2664-2674
Publication date:
2016-08-01
Acceptance date:
2016-07-17
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
642083
Keywords:
Pubs id:
pubs:642083
UUID:
uuid:8b37b3cb-0c57-47b4-a976-08cb496a0039
Local pid:
pubs:642083
Deposit date:
2017-02-08

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