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Oxidation of cysteine by electrogenerated octacyanomolybdate(v)

Abstract:

We report on the response of solid carbon electrodes (glassy carbon and boron doped diamond to the one electron oxidation of octacyanomolybdate(IV) in a wide pH range (1-11). Under alkaline conditions the oxidation of octacyanomolybdate(IV) was found to proceed via a EC reaction mechanism, where one electron oxidation to octacyanomolybdate(V) was followed by inner sphere decomposition of the oxidised species. Further, the electrochemical oxidation of octacyanomolybdate(IV) was studied in the ...

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Publication status:
Published

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Publisher copy:
10.1039/b400141a

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume:
6
Issue:
6
Pages:
1316-1320
Publication date:
2004-03-21
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
39055
Language:
English
Pubs id:
pubs:39055
UUID:
uuid:8b2172f6-1be6-44f8-8336-36a0cc23977e
Local pid:
pubs:39055
Deposit date:
2012-12-19

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