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Synthesis and characterization of the nine-atom, rhena- and tungsta-boranes (Cp*Re)(2)B7H7 and (Cp*W)(2)B7H9, Cp* = eta(5)-C5Me5. Molecular mimics of hypoelectronic main-group clusters in Zintl phases

Abstract:
Geometric and molecular orbital analyses of the metallaboranes (Cp*Re)2B7H7 and (Cp*W)2B7H9, which display unusual, but identical, core structures and skeletal electron pair counts of n - 2, demonstrate a close connection between these molecular compounds and anionic, hypoelectronic main-group clusters found in the solid state.
Publication status:
Published

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Publisher copy:
10.1039/a805356a

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMICAL COMMUNICATIONS More from this journal
Issue:
17
Pages:
1787-1788
Publication date:
1998-09-07
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Pubs id:
pubs:51728
UUID:
uuid:8b1ccabe-19a4-4f8d-ac6e-0111254d43dd
Local pid:
pubs:51728
Source identifiers:
51728
Deposit date:
2012-12-19

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