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THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2

Abstract:

The 505←404, 404←303, 303←202 and 202←101 rotational transitions of the open-shell van der Waals complex ArNO2 have been observed using a Fourier-transform microwave spectrometer. The complex was produced by supersonic expansion of NO2 gas in argon. The spectrum showed fine, magnetic hyperfine and electric quadrupole structure. The data have been fitted to a semi- rigid Hamiltonian to determine the molecular parameters for the KitA=0 state. We discuss the implications of these derived paramet...

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Publication status:
Published

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Journal:
CHEMICAL PHYSICS LETTERS More from this journal
Volume:
222
Issue:
5
Pages:
443-449
Publication date:
1994-05-27
DOI:
ISSN:
0009-2614
Language:
English
Pubs id:
pubs:44531
UUID:
uuid:8ac03749-6ebf-4bc5-992e-8c69e1694af6
Local pid:
pubs:44531
Source identifiers:
44531
Deposit date:
2012-12-19

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