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Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode

Abstract:
The finite difference method in conjunction with a conformal mapping technique is used to simulate the diffusion limiting current for three different CE mechanisms at a microdisc electrode. Working surfaces are presented for the variation of the limiting current with a normalised homogeneous kinetic parameter and equilibrium constant. Empirical equations are given to describe the current when the homogeneous equilibrium position lies heavily in favour of the electroinactive species. © 2007 Elsevier B.V. All rights reserved.
Publication status:
Published

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Authors


Streeter, I More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
615
Issue:
2
Pages:
154-158
Publication date:
2008-04-15
DOI:
ISSN:
1572-6657
URN:
uuid:8aae2950-836a-42e0-9787-1a34079af962
Source identifiers:
40827
Local pid:
pubs:40827

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