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Control of valence states in Rh-doped TiO2 by Sb co-doping: A study by high resolution X-ray photoemission spectroscopy

Abstract:

The influence of antimony co-doping on the electronic structure of rutile rhodium-doped TiO 2 has been investigated by X-ray photoemission spectroscopy. Rh doping leads to the appearance of new Rh 4d states above the top of the O 2p valence band and the Fermi level shifts down from a position close to the conduction band minimum in undoped TiO 2 to deeper in the gap. Sb co-doping restores the Fermi level to the top of the bandgap. These changes ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
515
Issue:
4-6
Pages:
249-253
Publication date:
2011-10-27
DOI:
ISSN:
0009-2614
Language:
English
Pubs id:
pubs:206158
UUID:
uuid:8a75ee89-d460-42a5-a590-419f2bda028b
Local pid:
pubs:206158
Source identifiers:
206158
Deposit date:
2012-12-19

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