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Dynamics of ion transfer potentials at liquid-liquid interfaces.

Abstract:

The Nernst-Planck-Poisson finite difference method is used to simulate the dynamic evolution of a water-nitrobenzene system with initially equimolar concentrations of a monovalent salt present in both liquids. The effect of single ion partition coefficients on the evolution of the liquid junction is investigated. The results from simulations reveal two separable components of the potential difference, similar to the behavior observed in recent works on the dynamic theory of membrane potential...

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Publication status:
Published

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Publisher copy:
10.1021/jp202318y

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The journal of physical chemistry. B
Volume:
115
Issue:
21
Pages:
6909-6921
Publication date:
2011-06-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:8a74867c-eadb-4b63-89dc-40a4f2f08588
Source identifiers:
138836
Local pid:
pubs:138836
Language:
English

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