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Application of copper(i) salt and fluoride promoted Stille coupling reactions in the synthesis of bioactive molecules

Abstract:
The Stille coupling between organostannanes and organohalides is an effective catalytic method for organic synthesis. Despite the ample amount of published results in this area, finding the optimal conditions for this transformation is often not straightforward. It was observed that this reaction could be accelerated with improved efficiency by the addition of a Cu(i) salt and fluoride. This review summarises the application of this simple protocol in the synthesis of natural products, their analogues and other biologically active molecules, from 2004 to 2018.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c9ob01602c

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Oriel College
Role:
Author
ORCID:
0000-0002-4032-6481


Publisher:
Royal Society of Chemistry
Journal:
Organic and Biomolecular Chemistry More from this journal
Volume:
17
Pages:
9095-9123
Publication date:
2019-09-20
Acceptance date:
2019-09-18
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
Pmid:
31596305


Language:
English
Keywords:
Pubs id:
pubs:1061697
UUID:
uuid:8a019372-9a60-4a91-9a5a-2bedbeb47ac0
Local pid:
pubs:1061697
Source identifiers:
1061697
Deposit date:
2019-11-05

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