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Journal article

A zwitterionic hydrocarbon-soluble borenium ion based on a β-diketiminate backbone.

Abstract:
A versatile synthetic route has been developed to access strongly Lewis acidic borenium cations (and heavier group 13 analogues) featuring a pendant weakly-coordinating borate function. The hydrocarbon-soluble borenium/borate zwitterion is more strongly Lewis acidic than B(C6F5)3, despite featuring a pendant (non-fluorinated) aryl group and two flanking N-donors.
Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/c7cc03121a

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Queens College
Role:
Author
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
44
Pages:
5981-5984
Publication date:
2017-05-11
Acceptance date:
2017-05-09
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
28513661
Language:
English
Keywords:
Pubs id:
pubs:695803
UUID:
uuid:89d8e363-68ab-4325-a6cf-0988f017f800
Local pid:
pubs:695803
Source identifiers:
695803
Deposit date:
2017-09-22

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