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Observation of staging during intercalation in layered alpha-cobalt hydroxides: a synthetic and kinetic study.

Abstract:

The anion-exchange reaction of the layered alpha-cobalt hydroxides Co(OH)(1.75)(DDS)(0.25).0.6H(2)O (1) and Co(OH)(1.7)Cl(0.3).0.4H(2)O (3) with carbonate has been investigated. For 3 the reaction proceeds by complete displacement of the interlayer Cl(-) anions by CO(3)(2-) to give Co(OH)(1.7)(CO(3))(0.15).0.6H(2)O (4). Remarkably for 1 we only observe ion-exchange of the DDS(-) from every other layer to give the second stage intercalate Co(OH)(1.75)(DDS)(0.07)(CO(3))(0.09).0.5H(2)O (2). The ...

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Publication status:
Published

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Publisher copy:
10.1021/ic801639e

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Inorganic chemistry
Volume:
47
Issue:
24
Pages:
11839-11846
Publication date:
2008-12-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:89d673c1-d6af-45fb-b09f-8ff3604d71b8
Source identifiers:
51258
Local pid:
pubs:51258
Language:
English

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