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A study of atom and radical kinetics

Abstract:

This thesis describes the measurement of rate constants for gas phase reactions as a function of temperature (285 ≤ T/K ≤ 850) and pressure (48 ≤ P/Torr ≤ 700). One or both reactants was monitored directly in real time, using time–resolved resonance fluorescence (for atoms) and u.v. absorption (for radicals). Reactants were produced by exciplex laser flash photolysis. The technique was used to measure rate constants to high precision for the following reactions under the stated conditions: • ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
Jesus College
Role:
Author
More by this author
Division:
MPLS
Department:
Chemistry
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
1990
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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