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Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights into electron transfer processes based on the asymmetric Marcus-Hush model

Abstract:

In this study, variable temperature experiments have been used in conjunction with numerical fitting of cyclic and square wave voltammogram responses via the asymmetric version of Marcus theory to provide molecular insight into the electroreduction of the 3-nitrophenolate anion in DMSO on mercury hemispherical microelectrodes of 23 μm radius. As a result, the reorganization energy, differences between the inner-sphere force constants of the electroactive species, and the degree of adiabaticit...

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Journal:
Electrochimica Acta
Volume:
110
Pages:
772-779
Publication date:
2013-01-01
DOI:
ISSN:
0013-4686
Source identifiers:
443096
Language:
English
Keywords:
Pubs id:
pubs:443096
UUID:
uuid:89b4dbae-0fa8-4c50-accf-a71bccf781f7
Local pid:
pubs:443096
Deposit date:
2014-02-10

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