Journal article icon

Journal article

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights into electron transfer processes based on the asymmetric Marcus-Hush model

Abstract:

In this study, variable temperature experiments have been used in conjunction with numerical fitting of cyclic and square wave voltammogram responses via the asymmetric version of Marcus theory to provide molecular insight into the electroreduction of the 3-nitrophenolate anion in DMSO on mercury hemispherical microelectrodes of 23 μm radius. As a result, the reorganization energy, differences between the inner-sphere force constants of the electroactive species, and the degree of adiabaticit...

Expand abstract

Actions


Access Document


Authors


Laborda, E More by this author
Suwatchara, D More by this author
Henstridge, MC More by this author
Expand authors...
Journal:
Electrochimica Acta
Volume:
110
Pages:
772-779
Publication date:
2013
DOI:
ISSN:
0013-4686
URN:
uuid:89b4dbae-0fa8-4c50-accf-a71bccf781f7
Source identifiers:
443096
Local pid:
pubs:443096

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP