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Palladium nanoparticle-modified carbon nanotubes for electrochemical hydrogenolysis in ionic liquids

Abstract:

The electrochemical hydrogenolysis of benzyl and carboxybenzyl protecting groups is described. Optimisation of a synthetic protocol afforded well-defined palladium (Pd) nanoparticles on the surface of multiwall carbon nanotubes (CNTs). The high surface area composite was investigated, and differences observed in the voltammetry for the same composite in aqueous and ionic liquid systems are discussed. When used to reduce acidic protons in the ionic liquid (IL) 1-ethy-3-methylimidazolium bis(tr...

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Publication status:
Published

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Publisher copy:
10.1039/c1nj20070d

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
35
Issue:
7
Pages:
1369-1375
Publication date:
2011-01-01
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
Language:
English
Pubs id:
pubs:164300
UUID:
uuid:89850972-3296-42f9-ad00-e4f2876c44a1
Local pid:
pubs:164300
Source identifiers:
164300
Deposit date:
2012-12-19

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