- Abstract:
- A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C(60) and C(70) with association constants of 2 x 10(6) and 2 x 10(8) M(-1), respectively, in toluene. Its affinities for C(86) and La@C(82) are too strong to measure by fluorescence titration. The solvent dependence of the association constants shows that solvation of both the guest and the host influence the binding strength.
- Publication status:
- Published
- Publisher copy:
- 10.1021/ol101393h
-
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- Journal:
- Organic letters
- Volume:
- 12
- Issue:
- 15
- Pages:
- 3544-3547
- Publication date:
- 2010-08-05
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- URN:
-
uuid:89549dda-b859-4c6a-be41-6bb8efaf415c
- Source identifiers:
-
65253
- Local pid:
- pubs:65253
- Language:
- English
- Copyright date:
- 2010
Journal article
A cyclic porphyrin trimer as a receptor for fullerenes.
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