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A cyclic porphyrin trimer as a receptor for fullerenes.

Abstract:
A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C(60) and C(70) with association constants of 2 x 10(6) and 2 x 10(8) M(-1), respectively, in toluene. Its affinities for C(86) and La@C(82) are too strong to measure by fluorescence titration. The solvent dependence of the association constants shows that solvation of both the guest and the host influence the binding strength.
Publication status:
Published

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Publisher copy:
10.1021/ol101393h

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Journal:
Organic letters
Volume:
12
Issue:
15
Pages:
3544-3547
Publication date:
2010-08-01
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
Source identifiers:
65253
Language:
English
Pubs id:
pubs:65253
UUID:
uuid:89549dda-b859-4c6a-be41-6bb8efaf415c
Local pid:
pubs:65253
Deposit date:
2012-12-19

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