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Crystal and magnetic structures of Ba4Mn3O10

Abstract:

A polycrystalline sample of Ba4Mn3O10 has been prepared and characterized by X-ray diffraction (290 K), neutron diffraction (290, 80, 5K) and magnetometry (5 ≤ T(K) ≤ 1000). At 290 K the compound is paramagnetic and isostructural with Ba4Ti2PtO10. Mn3O12 trimers, built up from MnO6 octahedra, are linked through common vertices to form corrugated sheets perpendicular to the y-axis of the orthorhombic unit cell (Space group Cmca, a = 5.6850(1), b = 13.1284(1), c = 12.7327(1) Å); Ba atoms occupy...

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Publication status:
Published

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Publisher copy:
10.1006/jssc.2002.9658

Authors


Zubkov, VG More by this author
Tyutyunnik, AP More by this author
Berger, IF More by this author
Voronin, VI More by this author
Bazuev, GV More by this author
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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
167
Issue:
2
Pages:
453-458
Publication date:
2002-09-05
DOI:
ISSN:
0022-4596
URN:
uuid:88803e58-2496-42a2-a8b4-da3bdd839cbf
Source identifiers:
38440
Local pid:
pubs:38440
Language:
English

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