- Abstract:
-
The alkylation reactions of enolates derived from the highly diastereoselective conjugate additions of lithium (R)-N-benzyl-N-α-methylbenzylamide (R)-1 to N,N-dimethyl crotonamide 2 and N,N-dimethyl cinnamide 3 have been investigated. The alkylations of enolates derived from 3 are shown to afford anti-α-alkyl-β-amino carboxamides with excellent stereocontrol: the stereochemistry is assigned with the aid of a single crystal X-ray structure of (2R,3S,αR)-N,N-dimethyl 2-benzyl-3-phenyl-3-(N-benz...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/recl.19951140409
-
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- Journal:
- RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY
- Volume:
- 114
- Issue:
- 4-5
- Pages:
- 175-183
- Publication date:
- 1995-01-01
- DOI:
- ISSN:
-
0165-0513
- URN:
-
uuid:880d88c9-81ff-40ae-93ba-f177c7f3169c
- Source identifiers:
-
168595
- Local pid:
- pubs:168595
- Keywords:
- Copyright date:
- 1995
Journal article
ASYMMETRIC-SYNTHESIS OF ANTI-ALPHA-ALKYL-BETA-AMINO CARBOXAMIDES
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