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Accessible sugars as asymmetric olefin epoxidation organocatalysts: glucosaminide ketones in the synthesis of terminal epoxides.

Abstract:
A systematically varied series of conformationally restricted ketones, readily prepared from N-acetyl-D-glucosamine, were tested against representative olefins as asymmetric epoxidation catalysts showing useful selectivities against terminal olefins and, in particular, typically difficult 2,2-disubstituted terminal olefins.
Publication status:
Published

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Publisher copy:
10.1039/b911675c

Authors


Boutureira, O More by this author
McGouran, JF More by this author
Stafford, RL More by this author
Emmerson, DP More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
Organic and biomolecular chemistry
Volume:
7
Issue:
20
Pages:
4285-4288
Publication date:
2009-10-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:87b1300a-7790-4685-94ee-a38bf4855888
Source identifiers:
34912
Local pid:
pubs:34912

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