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Journal article

Macrocycle-supported titanium complexes with chelating imido ligands: analogues of ansa-metallocenes.

Abstract:

Reactions of 1,4-dimethyl-1,4,7-triazacyclononane (L1a) and 1,4-diisopropyl-1,4,7-triazacyclononane (L1b) to form 1-aminopropyl-4,7-di-R-1,4,7-triazacyclononane [R = Me (H2L3a) or Pri (H2L3b)] and 1-(2-aminobenzyl)-4,7-di-R-1,4,7-triazacyclononane [R = Me (H2L5a) or Pri (H2L5b)] are reported. Reaction of H2L3a and H2L5a with [Ti(NMe2)2Cl2] gives the ansa-linked macrocycle-imido complexes [Ti(kappa 4-L3a)Cl2] (5a) and [Ti(kappa 4-L5a)Cl2] (6a), respectively, and NHMe2. Reaction of H2L3a with [...

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Publication status:
Published

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Publisher copy:
10.1021/ic9910357

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
39
Issue:
24
Pages:
5483-5491
Publication date:
2000-11-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
51021
Language:
English
Pubs id:
pubs:51021
UUID:
uuid:878bdaff-cb58-42d8-981c-f786c9e0b399
Local pid:
pubs:51021
Deposit date:
2012-12-19

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