Journal article
Macrocycle-supported titanium complexes with chelating imido ligands: analogues of ansa-metallocenes.
- Abstract:
-
Reactions of 1,4-dimethyl-1,4,7-triazacyclononane (L1a) and 1,4-diisopropyl-1,4,7-triazacyclononane (L1b) to form 1-aminopropyl-4,7-di-R-1,4,7-triazacyclononane [R = Me (H2L3a) or Pri (H2L3b)] and 1-(2-aminobenzyl)-4,7-di-R-1,4,7-triazacyclononane [R = Me (H2L5a) or Pri (H2L5b)] are reported. Reaction of H2L3a and H2L5a with [Ti(NMe2)2Cl2] gives the ansa-linked macrocycle-imido complexes [Ti(kappa 4-L3a)Cl2] (5a) and [Ti(kappa 4-L5a)Cl2] (6a), respectively, and NHMe2. Reaction of H2L3a with [...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ic9910357
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Bibliographic Details
- Journal:
- Inorganic chemistry
- Volume:
- 39
- Issue:
- 24
- Pages:
- 5483-5491
- Publication date:
- 2000-11-01
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- Source identifiers:
-
51021
Item Description
- Language:
- English
- Pubs id:
-
pubs:51021
- UUID:
-
uuid:878bdaff-cb58-42d8-981c-f786c9e0b399
- Local pid:
- pubs:51021
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2000
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