Journal article icon

Journal article

Synthesis and characterization of a novel N-F reagent derived from the ethano-Troger's base: (1)JFN coupling constants as a signature for the N-F bond.

Abstract:
Methylation of 2,8-dimethyl-6H,12H-5,11-ethanodibenzo[b,f][1,5]-diazocine (ethano-Tröger's base) with methyl iodide followed by ion metathesis and fluorination with N-fluoro-2,3,4,5,6-pentachloropyridinium triflate affords a new electrophilic N-F reagent, that is more reactive than Selectfluor. 2D (19)F-(15)N HMQC experiments provide (1)JNF coupling constants which are diagnostic for the N-F functional group.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

Actions


Access Document


Publisher copy:
10.1039/c5cc08375c

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Role:
Author
Expand authors...
More from this funder
Funding agency for:
Wolstenhulme, J
More from this funder
Funding agency for:
Cvengroš, J
More from this funder
Grant:
Doc.Mobility project P1EZP2_155528
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
52
Issue:
8
Pages:
1606-1609
Publication date:
2015-11-25
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:86a7a0e2-9f81-4700-bcfc-0630e69fc900
Source identifiers:
588839
Local pid:
pubs:588839
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP