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Thesis

Reactivity studies of the 2-phosphaethynolate anion: a pathway to phosphinecarboxamides

Abstract:

This thesis summarises the research carried out during my PhD on the phosphinecarboxamide family. Inspired by Wöhler’s seminal synthesis of urea, the phosphinecarboxamides are obtained by the reaction of the 2-phosphaethynolate anion, PCO–, a heavier congener of the cyanate anion, with ammonium salts. These species are phosphorus-containing analogues of urea, RHPC(O)NHR’. These compounds are prime examples of primary phosphines that exhibit remarkably air- and moisture stability. Several e...

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Division:
MPLS
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Depositor, Author

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Role:
Supervisor
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Grant:
Funding agency for:
de Faria, EN
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
UUID:
uuid:8699ae1c-f320-4e9d-8576-a46454ea29f5
Language:
English

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