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Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.

Abstract:
Molecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing of polymer strands (see scheme), a longer correlation length as compared with solvated oligomers is observed. Copyright © 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201004896

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Journal:
Angewandte Chemie (International ed. in English)
Volume:
49
Issue:
48
Pages:
9136-9139
Publication date:
2010-11-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:84bb4f7a-b4fa-4f49-a096-2db85bb041f0
Source identifiers:
107154
Local pid:
pubs:107154

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