- Abstract:
-
Polycrystalline samples of bulk composition Ba5Mn3PdO12, Ba6Mn4PdO15, and Ba7Mn5PdO18 have been synthesised and characterised by X-ray diffraction, electron diffraction and magnetometry. These compounds adopt a 2H-related crystal structure consisting of [001] chains of MnO6 and PdO6 polyhedra, with Ba2+ cations separating the chains. The three compounds, each of which is commensurate in the xy plane but incommensurate along the z axis, differ in the ratio of octahedra to trigonal prisms in th...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/a805935g
-
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- Journal:
- JOURNAL OF MATERIALS CHEMISTRY
- Volume:
- 9
- Issue:
- 2
- Pages:
- 479-483
- Publication date:
- 1999-02-05
- DOI:
- EISSN:
-
1364-5501
- ISSN:
-
0959-9428
- URN:
-
uuid:83d18b6f-c957-4320-8a8e-1f7b9466a462
- Source identifiers:
-
36849
- Local pid:
- pubs:36849
- Language:
- English
- Copyright date:
- 1999
Journal article
Incommensurate phases in the Ba-Mn-Pd-O system
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