- Abstract:
-
The compounds Sr4-xCaxIrO6 (x = 0.5, 1, 2, 3, 4) and Sr3MIrO6 (M = Li, Na, Zn, Cd) have been synthesized and studied by X-ray powder diffraction and SQUID magnetometry. They all adopt the K4CdCl6 structure, with the cations M and Ca occupying only the trigonal prismatic sites in the [001] chains unless x> 1. Those compounds which contain only IrIV order antiferromagnetically at temperatures between 14 and 22 K, and those which contain only IrV show temperature-independent paramagnetism. Th...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/jm9960600395
-
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- Journal:
- JOURNAL OF MATERIALS CHEMISTRY
- Volume:
- 6
- Issue:
- 3
- Pages:
- 395-401
- Publication date:
- 1996-03-05
- DOI:
- EISSN:
-
1364-5501
- ISSN:
-
0959-9428
- URN:
-
uuid:83c4345c-4525-4abc-b3d7-d57d77389369
- Source identifiers:
-
45188
- Local pid:
- pubs:45188
- Language:
- English
- Copyright date:
- 1996
Journal article
Structural and magnetic properties of Sr(4-x)M(x)IrO(6) (M=Ca, Zn, Cd, Li, Na)
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