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Three-component coordination networks based on [Ru(phen)(CN)4(2-) anions, near-infrared luminescent lanthanide(III) cations, and ancillary oligopyridine ligands: structures and photophysical properties.

Abstract:

A series of cyanide-bridged coordination networks has been prepared which contain [Ru(phen)(CN)4](2-) anions, Ln(III) cations, and additional oligopyridine ligands (1,10-phenanthroline, 2,2':6',2'''-terpyridine or 2,2'-bipyrimidine) which coordinate to the Ln(III) centres. Five structural types have been identified and examples of each type of structure are described: these are hexanuclear Ru4Ln2 clusters; two-dimensional Ru-Ln sheets with a honeycomb pattern of edge-linked Ru6Ln6 hexagons; o...

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Publication status:
Published

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Publisher copy:
10.1039/b702235b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
23
Pages:
2419-2430
Publication date:
2007-06-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:83bc2f70-b05a-4690-8483-d10c283c9363
Source identifiers:
46787
Local pid:
pubs:46787
Language:
English

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