- Abstract:
- The first total synthesis of erythroskyrine, a polyenoyltetramic acid mycotoxin and principal pigment of Pénicillium Islandicum Sopp., is described using a palladium(n) catalysed oxycarbonylation to create the furan-derived bicyclic portion 3 and the phosphonate ester 5 to furnish both the polyenoyl chain and the N-methyl (S)valine derived tetramic acid terminus.
- Publication status:
- Published
- Publisher copy:
- 10.1039/a809823i
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
- Issue:
- 8
- Pages:
- 839-841
- Publication date:
- 1999-04-21
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
1472-7781
- URN:
-
uuid:838b8837-4f8e-4b09-9f54-2bbcba39bef3
- Source identifiers:
-
52111
- Local pid:
- pubs:52111
- Language:
- English
- Copyright date:
- 1999
Journal article
Total synthesis of the polyenoyltetramic acid mycotoxin erythroskyrine
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