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Journal article

Total synthesis of the polyenoyltetramic acid mycotoxin erythroskyrine

Abstract:
The first total synthesis of erythroskyrine, a polyenoyltetramic acid mycotoxin and principal pigment of Pénicillium Islandicum Sopp., is described using a palladium(n) catalysed oxycarbonylation to create the furan-derived bicyclic portion 3 and the phosphonate ester 5 to furnish both the polyenoyl chain and the N-methyl (S)valine derived tetramic acid terminus.
Publication status:
Published

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Publisher copy:
10.1039/a809823i

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
8
Pages:
839-841
Publication date:
1999-04-21
DOI:
EISSN:
1364-5463
ISSN:
1472-7781
Source identifiers:
52111
Language:
English
Pubs id:
pubs:52111
UUID:
uuid:838b8837-4f8e-4b09-9f54-2bbcba39bef3
Local pid:
pubs:52111
Deposit date:
2012-12-19

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