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Superior anion induced shuttling behaviour exhibited by a halogen bonding two station rotaxane

Abstract:

Two bistable halogen and hydrogen bonding-naphthalene diimide [2]rotaxanes have been prepared and the system incorporating a halogen bond donor anion recognition site is demonstrated to exhibit superior anion induced translational motion of the macrocyclic wheel component relative to the hydrogen bonding analogue. Proton NMR spectroscopy is used to estimate the percentage occupancies of the macrocycle at the respective station and importantly indicates that the halogen bonding rotaxane displa...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/C6SC00783J

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
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Funding agency for:
Robinson, SW
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Funding agency for:
Robinson, SW
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Science Journal website
Publication date:
2016-04-28
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
URN:
uuid:833f7bfb-b8b3-4d5d-be59-ff56ea309a7e
Source identifiers:
634822
Local pid:
pubs:634822

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