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Thermal Generation and Structures of the Unsaturated Doubly Bridged Complex [Mo2Cp2Cl2(mu-SMe)(2)] and Its Quadruply Bridged Isomer [Mo2Cp2(mu-Cl)(2)(mu-SMe)(2)]

Abstract:

The doubly and quadruply bridged isomers [Mo2Cp 2Cl2(μ-SMe)2] (4) and [Mo2Cp 2(μ-Cl)2(μ-SMe)2] (3) have been obtained as side-products when the dicarbonyl precursor [Mo2Cp 2(CO)2(μ-SMe)3]Cl (1) is warmed in toluene solution, the main product being the tris-thiolato-bridged compound [Mo 2Cp2(μ-Cl)(μ-SMe)3] (2). Complex 4 is stable at room temperature but can be transformed into 3 at elevated temperatures. 3 and 4 have been crystallographically characterized, and both contain equivalent molybde...

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Publication status:
Published

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Publisher copy:
10.1021/om101061y

Authors


McGrady, JE More by this author
Petillon, FY More by this author
Schollhammer, P More by this author
Talarmin, J More by this author
Journal:
ORGANOMETALLICS
Volume:
30
Issue:
3
Pages:
649-652
Publication date:
2011-02-14
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:82684adb-bee3-4797-afab-723f445adf42
Source identifiers:
124456
Local pid:
pubs:124456
Language:
English

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