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Voltammetry in Weakly Supported Media: The Stripping of Thallium from a Hemispherical Amalgam Drop. Theory and Experiment

Abstract:

A theoretical model for electrochemical processes in resistive media is applied to interpret the current measured for the stripping of thallium from a Tl/Hg amalgam. Chronoamperometry is presented for a potential step experiment at a 12.5 μm radius hemispherical mercury drop in which thallium is first deposited and then stripped. Unusual features are observed in the transient stripping current, and it is proposed that these occur when the concentration of thallium(I) cations in solution is so...

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Publication status:
Published

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Publisher copy:
10.1021/jp8065426

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
112
Issue:
44
Pages:
17175-17182
Publication date:
2008-11-06
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Source identifiers:
40974
Language:
English
UUID:
uuid:823e5e4a-a0aa-4476-8449-8bcca93a7b08
Local pid:
pubs:40974
Deposit date:
2012-12-19

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