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Isolation, spectroscopic characterization and study of island formation of two isomers of the metallofullerene Nd@C82

Abstract:

Two types of the metallofullerene Nd@C82 have been isolated and characterized. HPLC was used to isolate Nd@C82(I, II). The two isomers were characterized by mass spectrometry and UV-Vis-N1R absorption spectroscopy. Nd@C82(I) was found to be similar in structure to the main isomer of other lanthanofullerenes such as La@C82. We assign Nd@C82(I) to have a C2v cage symmetry. Nd@C 82(II) showed a markedly different UV-Vis-NIR absorption spectrum to Nd@C82(I). Its spectrum is in good agreement with...

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Publisher copy:
10.1149/1.2214618

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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
Role:
Author
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Journal:
ECS Transactions
Volume:
1
Issue:
15
Pages:
43-49
Publication date:
2006-01-01
DOI:
EISSN:
1938-6737
ISSN:
1938-5862
URN:
uuid:81ef493a-6785-47c9-9c09-5e52b499a540
Source identifiers:
134251
Local pid:
pubs:134251
Language:
English

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