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Controlling Magnetic Order and Quantum Disorder in Molecule-Based Magnets

Abstract:

We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H2O)(gly)2](ClO4)2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics
Role:
Author
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Publisher:
American Physical Society
Journal:
PHYSICAL REVIEW LETTERS
Volume:
112
Issue:
20
Publication date:
2014-05-19
DOI:
EISSN:
1079-7114
ISSN:
0031-9007
URN:
uuid:81acdbb9-10ab-44c8-9eff-713bd5ca337e
Source identifiers:
466851
Local pid:
pubs:466851
Language:
English

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