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Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane.

Abstract:
The first example of utilizing halogen-bonding anion recognition to facilitate molecular motion in an interlocked structure is described. A halogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttling of the macrocycle component from the hydrogen-bonding station to the halogen-bonding station upon iodide recognition. In contrast, chloride-anion binding reinforces the macrocycle to reside at the hydrogen-bonding station.
Publication status:
Published

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Publisher copy:
10.1002/anie.201407580

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
Wiley
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
53
Issue:
44
Pages:
11854-11858
Publication date:
2014-10-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:484058
UUID:
uuid:819e12a5-a5a1-4b74-a118-abd3e5415f57
Local pid:
pubs:484058
Source identifiers:
484058
Deposit date:
2014-09-22

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