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Abrasively modified electrodes: mathematical modelling and numerical simulation of electrochemical dissolution/growth processes under cyclic voltammetric conditions

Abstract:

An approximate mathematical model for electrochemical dissolution/growth processes of diffusionally independent and well-separated particles randomly dispersed on an inert conducting electrode surface is presented and solved using numerical simulation. The model, mimicking abrasively modified electrodes where particles of electroactive voltammograms solid are immobilised on an electrode surface, provides clear insights into the effects of different parameters on the voltammetric response of s...

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Publication status:
Published

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Publisher copy:
10.1007/s10008-006-0152-9

Authors


Chevallier, FG More by this author
Goodwin, A More by this author
Jones, TGJ More by this author
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Journal:
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume:
10
Issue:
10
Pages:
857-864
Publication date:
2006-10-05
DOI:
EISSN:
1433-0768
ISSN:
1432-8488
URN:
uuid:818b40f9-0728-4d02-b0f0-ab3160fa390a
Source identifiers:
40004
Local pid:
pubs:40004

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