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Main-chain metallopolymers at the static–dynamic boundary based on nickelocene

Abstract:

Interactions between metal ions and ligands in metal-containing polymers involve two bonding extremes: persistent covalent bonding, in which the polymers are essentially static in nature, or labile coordination bonding, which leads to dynamic supramolecular materials. Main-chain polymetallocenes based on ferrocene and cobaltocene fall into the former category because of the presence of strong metal–cyclopentadienyl bonds. Herein, we describe a main-chain polynickelocene—formed by ring-opening...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1038/nchem.2743

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Role:
Author
ORCID:
0000-0001-9404-0422
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Publisher:
Springer Nature Publisher's website
Journal:
Nature Chemistry Journal website
Volume:
9
Issue:
8
Pages:
743-750
Publication date:
2017-03-14
Acceptance date:
2017-01-26
DOI:
EISSN:
1755-4349
ISSN:
1755-4330
Pubs id:
pubs:710899
URN:
uri:8165a312-5df9-4175-ba9a-9978344fcc47
UUID:
uuid:8165a312-5df9-4175-ba9a-9978344fcc47
Local pid:
pubs:710899

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