- Abstract:
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Interactions between metal ions and ligands in metal-containing polymers involve two bonding extremes: persistent covalent bonding, in which the polymers are essentially static in nature, or labile coordination bonding, which leads to dynamic supramolecular materials. Main-chain polymetallocenes based on ferrocene and cobaltocene fall into the former category because of the presence of strong metal–cyclopentadienyl bonds. Herein, we describe a main-chain polynickelocene—formed by ring-opening...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 209.8KB)
-
- Publisher copy:
- 10.1038/nchem.2743
-
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- Publisher:
- Springer Nature Publisher's website
- Journal:
- Nature Chemistry Journal website
- Volume:
- 9
- Issue:
- 8
- Pages:
- 743-750
- Publication date:
- 2017-03-14
- Acceptance date:
- 2017-01-26
- DOI:
- EISSN:
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1755-4349
- ISSN:
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1755-4330
- Pubs id:
-
pubs:710899
- URN:
-
uri:8165a312-5df9-4175-ba9a-9978344fcc47
- UUID:
-
uuid:8165a312-5df9-4175-ba9a-9978344fcc47
- Local pid:
- pubs:710899
- Copyright holder:
- Musgrave et al.
- Copyright date:
- 2017
- Notes:
-
This is the accepted manuscript version of the article. The final version is available online from Springer Nature at: https://doi.org/10.1038/nchem.2743
Journal article
Main-chain metallopolymers at the static–dynamic boundary based on nickelocene
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