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EXPERIMENTAL AND RRKM MODELING STUDY OF THE CH3+H AND CH3+D REACTIONS

Abstract:

Rate coefficients for the reactions CH3 + H and CH3 + D are presented over the temperature ranges 300 ≤ T/K ≤ 600 and 289 ≤ T/K ≤ 400, respectively. The laser flash photolysis (193 nm) of acetone or acetone/N2O/D2 mixtures was employed to generate CH3 and H or CH3 and D, respectively, and the time dependences of the atom and radical concentrations were monitored by resonance fluorescence and absorption, respectively. Over the experimental pressure range (25-600 Torr of He) the CH3 + H reactio...

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Publication status:
Published

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Publisher copy:
10.1021/j100347a037

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
MACPHERSON, M More by this author
PILLING, M More by this author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY
Volume:
93
Issue:
10
Pages:
4047-4059
Publication date:
1989-05-18
DOI:
ISSN:
0022-3654
URN:
uuid:81573041-ae2f-4672-bab8-489ed68c7343
Source identifiers:
52544
Local pid:
pubs:52544
Language:
English

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