Journal article icon

Journal article

PHOTOELECTROCHEMICAL OXIDATION OF TRIS(DIMETHYLDITHIOCARBAMATO-S,S')COBALT(III)

Abstract:

The electro-oxidation of tris(dimethyldithiocarbamato-S,S′)cobalt(III), [Co(S2CNMe2)3], at platinum electrodes in acetonitrile solution in the presence of light of wavelengths between 300 and 600 nm gave rise to appreciable photocurrents. These are suggested to arise from an absorption of light by the one-electron oxidation product [Co(S2CNMe2)3]+ which is followed by an internal redox reaction which leads to the fragmentation of the cation and the probable formation of [Co(S2CNMe2)2] and oxi...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/dt9950001917

Authors


Expand authors...
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
12
Pages:
1917-1920
Publication date:
1995-06-21
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
URN:
uuid:81149f49-3834-424b-bd93-69334791b380
Source identifiers:
44869
Local pid:
pubs:44869
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP