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Effect of pH on hydrogen pick-up and corrosion in zircaloy-4

Abstract:

Thermal Desorption Spectroscopy (TDS) has been used to investigate the hydrogen pick-up behaviour in different samples of Zircaloy-4. This includes as-received, cold rolled, hydrogen charged, and autoclave-oxidised in pure water and at an elevated pH (with 50% deuterated water) compared to commercial reactors. A characteristic desorption peak for hydrogen has been found at ~650°C, which is theorised to come from hydrides1. Cold rolled samples show the same general shape spectrum as the as-...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1007/978-3-319-67244-1_74

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Materials
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Materials
Oxford college:
St Edmund Hall
Publisher:
Springer Publisher's website
Pages:
1169-1180
Publication date:
2017-10-07
Acceptance date:
2017-02-22
DOI:
ISSN:
2367-1696 and 2367-1181
Pubs id:
pubs:828103
URN:
uri:80e4943d-b46c-468d-8a1a-639b2c42d3f9
UUID:
uuid:80e4943d-b46c-468d-8a1a-639b2c42d3f9
Local pid:
pubs:828103
ISBN:
9783030046385

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