Journal article icon

Journal article

Glycosyl disulfides: novel glycosylating reagents with flexible aglycon alteration.

Abstract:

[reaction: see text] Glycosyl disulfides have been shown for the first time to be effective glycosyl donors. Glucosylation and galactosylation of a panel of representative alcohol acceptors allowed the formation of 28 simple glycosides, disaccharides, and glycoamino acids in yields of up to 90%. As well as providing a novel class of effective glycosyl donors, the ability to easily alter the nature of the aglycon and the ability to differently activate donors that differ only in their aglycon ...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/jo051374j

Authors


Grayson, EJ More by this author
Rendle, PM More by this author
Gamblin, DP More by this author
Expand authors...
Journal:
The Journal of organic chemistry
Volume:
70
Issue:
24
Pages:
9740-9754
Publication date:
2005-11-05
DOI:
EISSN:
1520-6904
ISSN:
0022-3263
URN:
uuid:801b71b7-d256-4dbc-ba2a-869b3e130a3f
Source identifiers:
52064
Local pid:
pubs:52064

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP