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Halide abstraction as a route to cationic transition-metal complexes containing two-coordinate gallium and indium ligand systems

Abstract:

Halide abstraction chemistry offers a viable synthetic route to the cationic two-coordinate complexes [{Cp*Fe(CO)2} 2(μ-E)]+ (7, E = Ga; 8, E = In) featuring linear bridging gallium or indium atoms. Structural, spectroscopic, and computational studies undertaken on 7 are consistent with appreciable Fe-Ga π-bonding character; in contrast, the indium-bridged complex 8 is shown to feature a much smaller π component to the metal-ligand interaction. Analogous reactions utilizing the supermesityl-s...

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Publication status:
Published

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Publisher copy:
10.1021/om0506318

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Coombs, ND More by this author
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Journal:
ORGANOMETALLICS
Volume:
24
Issue:
24
Pages:
5891-5900
Publication date:
2005-11-21
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:7febd655-c2d6-4909-a432-6eaa59886ad5
Source identifiers:
46052
Local pid:
pubs:46052
Language:
English

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