- Abstract:
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High-resolution X-ray and neutron powder diffraction are used to reveal details of the spin-reorientation transition in the layered oxide pnictide CeMnAsO. Above 38 K, the localized moments on Mn(2+) are antiferromagnetically ordered in a checkerboard fashion within the antifluorite-type MnAs planes and are oriented perpendicular to the planes. Below 38 K, reorientation of these moments into the planes commences. This is complete by 34 K and is coincident with long-range ordering of the Ce(3+...
Expand abstract - Publisher copy:
- 10.1021/ic5026608
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- Journal:
- Inorganic chemistry
- Publication date:
- 2014-12-05
- DOI:
- EISSN:
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1520-510X
- ISSN:
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0020-1669
- URN:
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uuid:7f6b0cc3-b319-4fd8-8063-b8ac30a01c37
- Source identifiers:
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492038
- Local pid:
- pubs:492038
- Language:
- English
- Copyright date:
- 2014
Journal article
Spin-Reorientation Transition in CeMnAsO.
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