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Spin-Reorientation Transition in CeMnAsO.

Abstract:

High-resolution X-ray and neutron powder diffraction are used to reveal details of the spin-reorientation transition in the layered oxide pnictide CeMnAsO. Above 38 K, the localized moments on Mn(2+) are antiferromagnetically ordered in a checkerboard fashion within the antifluorite-type MnAs planes and are oriented perpendicular to the planes. Below 38 K, reorientation of these moments into the planes commences. This is complete by 34 K and is coincident with long-range ordering of the Ce(3+...

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Publisher copy:
10.1021/ic5026608

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Publication date:
2014-12-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:7f6b0cc3-b319-4fd8-8063-b8ac30a01c37
Source identifiers:
492038
Local pid:
pubs:492038
Language:
English

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