- Abstract:
-
Modification of carbon materials such as graphite and glassy carbon in bulk quantities using diazonium salts is developed. We used both 4-nitrobenzenediazonium tetrafluoroborate and 1-antharaquinonediazonium chloride to modify graphite and glassy carbon surfaces. Experiments were carried out in the presence and absence of hypophosphorous acid and the mechanism involved in both cases were studied using cyclic voltammetry. The observed peak potentials for both the 4-nitrophenyl and 1-anthraquin...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/poc.1331
-
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- Journal:
- JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
- Volume:
- 21
- Issue:
- 6
- Pages:
- 433-439
- Publication date:
- 2008-06-05
- DOI:
- EISSN:
-
1099-1395
- ISSN:
-
0894-3230
- URN:
-
uuid:7ec19a06-7077-4515-8955-dbf14e24ea07
- Source identifiers:
-
40836
- Local pid:
- pubs:40836
- Language:
- English
- Keywords:
- Copyright date:
- 2008
Journal article
A mechanistic investigation into the covalent chemical derivatisation of graphite and glassy carbon surfaces using aryldiazonium salts
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