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A mechanistic investigation into the covalent chemical derivatisation of graphite and glassy carbon surfaces using aryldiazonium salts

Abstract:

Modification of carbon materials such as graphite and glassy carbon in bulk quantities using diazonium salts is developed. We used both 4-nitrobenzenediazonium tetrafluoroborate and 1-antharaquinonediazonium chloride to modify graphite and glassy carbon surfaces. Experiments were carried out in the presence and absence of hypophosphorous acid and the mechanism involved in both cases were studied using cyclic voltammetry. The observed peak potentials for both the 4-nitrophenyl and 1-anthraquin...

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Publication status:
Published

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Publisher copy:
10.1002/poc.1331

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume:
21
Issue:
6
Pages:
433-439
Publication date:
2008-06-01
DOI:
EISSN:
1099-1395
ISSN:
0894-3230
Source identifiers:
40836
Language:
English
Keywords:
Pubs id:
pubs:40836
UUID:
uuid:7ec19a06-7077-4515-8955-dbf14e24ea07
Local pid:
pubs:40836
Deposit date:
2012-12-19

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