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A group 13/group 17 analogue of CO and N2: coordinative trapping of the GaI molecule.

Abstract:

The first row diatomic molecules N2 and CO have played central roles in developing fundamental models of electronic structure, and their interactions with transition metals have been widely investigated. By contrast, the valence isoelectronic molecules EX (E = group 13 element, X = group 17 element) have yet to be isolated under ambient conditions, either as the "free" molecule or as a simple metal complex. Here, we find that iodide abstraction from Cp*Fe(dppe)(GaI2) yields the stable complex...

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Publication status:
Published

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Publisher copy:
10.1021/ja800876k

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society
Volume:
130
Issue:
16
Pages:
5449-5451
Publication date:
2008-04-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:7c7876eb-fd80-47eb-99a3-194cde5d2ac2
Source identifiers:
34188
Local pid:
pubs:34188
Language:
English

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