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ELECTRON-BEAM REDUCTION OF CUBIC Y-DOPED ZRO2(100) - A STUDY BY X-RAY PHOTOELECTRON-SPECTROSCOPY

Abstract:
Electron beam reduction of cubic Y(III)-doped ZrO2(100) has been studied by X-ray photoelectron spectroscopy. In the initial stages of irradiation with 2-keV electrons oxygen loss is accompanied by specific reduction of Zr(IV) to Zr(0) without concomitant reduction of Y(III). The cross section for oxygen desorption is estimated to be 3.9 × 10-20 cm2. Surface stoichiometry is restored by argon-ion bombardment. © 1987.
Publication status:
Published

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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
66
Issue:
2
Pages:
364-368
Publication date:
1987-02-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:7bc4122e-fae5-4be2-a546-f026014a05a3
Source identifiers:
42781
Local pid:
pubs:42781
Language:
English

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