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The Marcus-Hush model of electrode kinetics at a single nanoparticle

Abstract:
We examine the effect of the Marcus-Hush model of electrode kinetics on electron transfer at the surface of a single nanoparticle impacting an electode. Using numerical simulation we demonstrate the possibility of observing a kinetically limited steady state current which is smaller than the mass transport limiting current for such a system. © 2013 Elsevier B.V. All rights reserved.
Publication status:
Published

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Authors


Henstridge, MC More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
712
Pages:
14-18
Publication date:
2014
DOI:
ISSN:
1572-6657
URN:
uuid:7b005290-2091-434c-881a-475f0492dc2c
Source identifiers:
440918
Local pid:
pubs:440918

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