The Marcus-Hush model of electrode kinetics at a single nanoparticle
- We examine the effect of the Marcus-Hush model of electrode kinetics on electron transfer at the surface of a single nanoparticle impacting an electode. Using numerical simulation we demonstrate the possibility of observing a kinetically limited steady state current which is smaller than the mass transport limiting current for such a system. © 2013 Elsevier B.V. All rights reserved.
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