Speed dependent rotational angular momentum polarization of the O2 (a 1Deltag) fragment following ozone photolysis in the wavelength range 248-265 nm.
The translational anisotropy and rotational angular momentum polarization of a selection of rotational states of the O2 (a 1Deltag; v=0) photofragment formed from ozone photolysis at 248, 260, and 265 nm have been determined using the technique of resonance enhanced multiphoton ionization in combination with time of flight mass spectrometry. At 248 nm, the dissociation is well described as impulsive in nature with all rotational states exhibiting similarly large, near-limiting values for the ...Expand abstract
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