Journal article icon

Journal article

Regio- and enantioselective synthesis of allylic fluorides by electrophilic fluorodesilylation of allyl silanes.

Abstract:
Enantiopure N-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silanes in a conceptually new approach to the regio- and enantioselective formation of allylic fluorides (see scheme). Excellent conversions were observed in these reactions, which afforded the desired allylic fluorides with up to 96% ee.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1002/anie.200351405

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
Angewandte Chemie (International ed. in English)
Volume:
42
Issue:
28
Pages:
3291-3294
Publication date:
2003-07-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:7a8b81dd-c0c0-461a-8a93-c2c387397c67
Source identifiers:
32417
Local pid:
pubs:32417

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP