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Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights Into electron transfer processes based on the asymmetric Marcus-Hush model

Abstract:

In this study, variable temperature experiments have been used in conjunction with numerical fitting of cyclic and square wave voltammogram responses via the asymmetric version of Marcus theory to provide molecular insight into the electroreduction of the 3-nitrophenolate anion in DMSO on mercury hemispherical microelectrodes of 23 μm radius. As a result, the reorganization energy, differences between the inner-sphere force constants of the electroactive species, and the degree of adiabaticit...

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Publication status:
Published

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Authors


Laborda, E More by this author
Suwatchara, D More by this author
Henstridge, MC More by this author
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Journal:
ELECTROCHIMICA ACTA
Volume:
110
Pages:
772-779
Publication date:
2013-11-01
DOI:
ISSN:
0013-4686
URN:
uuid:7a88c834-04b7-4323-8d0c-8777cde9213e
Source identifiers:
379442
Local pid:
pubs:379442

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