- Abstract:
-
The conformations of two classes of 7-ring diphosphine metal chelate have been analysed, based on DIOP- or BINAP-type structures. A combination of X-ray analysis, DFT calculations, data analysis based on the CDS structure database and solution NMR studies has been employed. The conformational flexibility of DIOP-type structures has been endorsed, and the scope of BINAP complex flexibility defined. BINAP complexes possess an intrinsic conformational mobility. Analysis of the metal-adjacent tor...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.tetasy.2010.04.030
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
- Journal:
- TETRAHEDRON-ASYMMETRY
- Volume:
- 21
- Issue:
- 13-14
- Pages:
- 1737-1744
- Publication date:
- 2010-07-14
- DOI:
- EISSN:
-
1362-511X
- ISSN:
-
0957-4166
- URN:
-
uuid:79e763ff-617c-47c3-b793-e2b24487c942
- Source identifiers:
-
71229
- Local pid:
- pubs:71229
- Language:
- English
- Copyright date:
- 2010
Journal article
Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility
Actions
Access Document
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Bibliographic Details
Item Description
Terms of use
If you are the owner of this record, you can report an update to it here: Report update to this record