Journal article
Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility
- Abstract:
-
The conformations of two classes of 7-ring diphosphine metal chelate have been analysed, based on DIOP- or BINAP-type structures. A combination of X-ray analysis, DFT calculations, data analysis based on the CDS structure database and solution NMR studies has been employed. The conformational flexibility of DIOP-type structures has been endorsed, and the scope of BINAP complex flexibility defined. BINAP complexes possess an intrinsic conformational mobility. Analysis of the metal-adjacent tor...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/j.tetasy.2010.04.030
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Authors
Bibliographic Details
- Journal:
- TETRAHEDRON-ASYMMETRY
- Volume:
- 21
- Issue:
- 13-14
- Pages:
- 1737-1744
- Publication date:
- 2010-07-14
- DOI:
- EISSN:
-
1362-511X
- ISSN:
-
0957-4166
- Source identifiers:
-
71229
Item Description
- Language:
- English
- Pubs id:
-
pubs:71229
- UUID:
-
uuid:79e763ff-617c-47c3-b793-e2b24487c942
- Local pid:
- pubs:71229
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2010
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