- Abstract:
- Base-induced isomerisation of epoxide 9 gives an azanortricyclanol 10 which is a precursor for a novel free-radical induced rearrangement to 6-substituted 2-azabicyclo[2.2.1]-5-heptenes 14a-c; 14c (R = 6-chloro-3-pyridinyl) is converted to the epibatidine analogue 2.
- Publication status:
- Published
- Publisher copy:
- 10.1055/s-1998-1963
-
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- Journal:
- SYNLETT
- Volume:
- 1998
- Issue:
- 12
- Pages:
- 1349-1350
- Publication date:
- 1998-12-05
- DOI:
- EISSN:
-
1437-2096
- ISSN:
-
0936-5214
- URN:
-
uuid:79e48d64-7d66-496e-b5d4-68090a093071
- Source identifiers:
-
36873
- Local pid:
- pubs:36873
- Language:
- English
- Keywords:
- Copyright date:
- 1998
Journal article
An epoxide rearrangement-radical rearrangement approach to 6-substituted 2-azabicyclo[2.2.1]-5-heptenes: Synthesis of an epibatidine analogue
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