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A 2,3-butanedione protected chiral glycine equivalent - A new building block for the stereoselective synthesis of enantiopure N-protected α-amino acids

Abstract:
A new chiral glycine equivalent 7 has been synthesised from glycidol using a chiral memory protocol, and its use in the synthesis of N-Z protected α-amino acids was demonstrated in a series of diasteroselective lithium enolate alkylation reactions and subsequent acid hydrolyses.

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
9
Issue:
4
Pages:
468-469
Publication date:
2003-02-21
ISSN:
1359-7345
Source identifiers:
327089
Language:
English
Pubs id:
pubs:327089
UUID:
uuid:79c324bc-8bf1-4c5b-8b44-7af4c588f340
Local pid:
pubs:327089
Deposit date:
2012-12-20

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