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New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand.

Abstract:
Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal Ti=N-NR2 functional group are described, along with the highly selective room temperature insertion of alkynes into the N-N bond of Ti{MeN(CH2CH2NSiMe3)2}(NNPh2)(py) and the catalytic cis-diamination of PhC[triple bond]CMe by diphenylhydrazine.
Publication status:
Published

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Publisher copy:
10.1039/b711941k

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Journal:
Chemical communications (Cambridge, England)
Issue:
46
Pages:
4937-4939
Publication date:
2007-12-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:798dd534-c337-4b70-a487-fc40f7fb2c4d
Source identifiers:
51053
Local pid:
pubs:51053

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